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Condensate recovery is among the areas of energy source conservation so widely applied in industrial sectors today. Condensate still contains about 20% of unhealthy steam, and it is distilled mineral water, almost totally free of dissolved solid waste. Therefore , it is recovery provides advantages to boilers that include reducing petrol costs, lowering chemical treatment, conserving water, and increasing central heating boiler efficiency. Non-contaminated condensate, which can be the product of non-contact water vapor application, returns to water vapor boiler's program as give food to water. You will discover two types in condensate obtaining system through boilers supports the pressurized condensate system and the gravity-vented condensate system. The display steam from high pressure condensate is hauled by revisiting this condensate to the deaerator while the gravity-vented condensate results to the furnace feed reservoir.

Oxygen Attack

Often people reported due to its pureness in characteristics; steam condensate requires simply no chemical cure, but usually so? Condensate is corrosive and can be infected by rusts, something that hardly any people are informed. Sometimes, condensate can be a bit acidic. This is exactly why condensate piping deteriorates swifter than heavy steam piping. Air corrosion takes place in condensate piping because pitting, which can be the most destructive form of corrode.

The reaction in oxygen invasion is:

4Fe + 6H2O + 3O2 → 4Fe(OH)3

Carbonic acid solution thins condensate pipes to result in grooving at the end section of the pipes. The result is, whether a condensate tubing has mainly pitting, the condensate is high in oxygen, however, if the pipe outlet is thinning hair, the condensate pipe experiences carbonic acid solution attack. Yet , where do oxygen and carbon dioxide for condensate piping originate from? Are generally not all wiped out oxygen and carbon dioxide in boiler liquid arrested by artificial means by the deaerator and chemically by sodium sulphite or perhaps DEHA from the boiler? Truly, there are two main reasons with this phenomenon. First of all, when heavy steam condenses, the flow volume shrinks therefore allowing fresh air to integrate and dissolve. Secondly, fresh air can also be pulled into condensate system through condensate high heels, leaking heating exchangers, and vents from condensate obtaining tanks.

Chemical p Corrosion

Co2 can get into in the same way as oxygen, even so, the main way to obtain carbon dioxide for steam is definitely the breakdown of bicarbonate and carbonate alkalinity in furnace water to form carbon dioxide.

Here i will discuss the tendencies that happen:

Carbonate effect: CO3 + H2O → CO2 + 2OH

Bicarbonate reaction: 2HCO3 + warmth → CARBON DIOXIDE + 2H2O

Carbon dioxide blends with vapor, condenses in condensate to form weak carbonic acid, and lowers the pH. Condensate is so 100 % pure that also small amount of fragile carbonic stomach acid can drop the ph level to 5. 5.

The response is:

CO2 + H2O → H2CO3

In Malaysia, there was a case in a petrochemical industry exactly where less than 20% of the condensate was delivered into the central heating boiler because of carbonic acid infiltration. In boiler, acidic condensate lowers pH, erodes sheet metal, increases break up iron, and increases the total dissolved solid waste (TDS) seeing that iron bicarbonate. Iron bicarbonate mixes with boiler mineral water to form iron bars oxide and carbon dioxide, and therefore the co2 mixes with steam once again. That is why some people cannot keep up a high pH in their central heating boiler despite doubling the dosing of caustic soda. in condensate recovery is certainly disadvantageous to steam central heating boiler and should be prevented.


Protection of after-boiler condensate lines is necessary. Corrosion on condensate series can be minimized by changeable amines because corrosion inhibitors. Volatile amines commonly used meant for condensate collection protection today are neutralizing amines and filming amines. Neutralizing amines react with carbonic acid solution and carbon dioxide to increase condensate pH to 9. One of the commonly used normalizing amines is certainly cyclohexylamine. Filming amines, on the flip side, form defensive films in metal surfaces and guard from much needed oxygen attack, the same way magnetite film does. One of filming amines is octyldecylamine. Having oil-like property, filming amines cover the metallic surface with one-molecule wide. Filming amines have no effect on condensate ph level. Carbon dioxide and oxygen tend to be corrosive in combination. Accordingly, if the system confronts both fresh air and acidity attacks, different both amines is always encouraged.

Besides chemical type treatment, condensate quality monitoring should be integrated on the daily or 7 days a week basis. Create a test of condensate to monitor flat iron content, firmness, and TDS. Check for colouring and purchase. Any difference indicates the wrong type of treatment or maybe contamination. Condensate is not cured to remove toxic contamination, therefore , to avoid iron hydroxide infiltration; permanent magnetic filter may be applied to eliminate it from condensate. Total golf club in central heating boiler feed liquid for medium sized pressure central heating boiler should be minimal than 0. 05 ppm, and any increase can mean iron hydroxide infiltration from the condensate line. To get boiler functioning below 2 0 bars, a suggested alkalinity ranking is one hundred forty to 800 ppm. In the event the alkalinity level exceeds 800 ppm, bicarbonate and carbonate will break up producing co2 and entrain in steam, as stated just before. However , the most effective method is to eliminate the alkaline firmness (carbonate and bicarbonate) decisivelydefinitively, determinately, once and for all, once for all by using the reverse-osmosis system as well as demineralization.


Finally, condensate is corrosive and harmful to condensate piping. The risk happens when many steam technical engineers, based on good boiler standard water field-test effects, feel comfortable with their particular boiler standard water treatments. Several engineers do not ever seriously consider and even realize the actual damage that could happen to all their condensate marks. This is a critical negligence. In the event that leaks soon after leaks are detected, it is actually too late and costly auto repairs would be expected. It is the remedying of condensate profit that makes it needless to replace condensate piping for quite some time.